MissingRemote have a article on migrating away from Windows Home Server Drive Extender which explains how to migrate your data out of the drive pool from version 1 of WHS to Windows Home Server 2011. The explained process will also work if you intend to move to any alternative "drive pool" solution, such as FlexRAID, unRAID, FreeNAS, or the couple of 3rd party add-ins which are available for WHS 2011.
Its a great comprehensive guide which you can find here.
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